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药物分析化学汉英词汇(2)

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原子荧光分光光度法:atomic fluorescence spectrophotometry,AFS第十六章 核磁共振波谱法核磁共振:nuclear magnetic resonance,NMR核磁共振波谱:NMR spectrum核磁共振波谱法:NMR spectroscopy扫场:swept field扫频:seept frequency连续波核磁共振:continuous wave NMR,CW NMRFourier变换NMR:PFT-NMR,FT-NMR二维核磁共振谱:2D-NMR质子核磁共振谱:proton magnetic resonance spectrum,PMR氢谱:1H-NMR碳-13核磁共振谱:13C-NMR spectrum,13CNMR自旋角动量:spin angular momentum磁旋比:magnetogyric ratio磁量子数:magnetic quantum number,m进动:precession弛豫历程:relaxation mechanism局部抗磁屏蔽:local diamagnetic shielding屏蔽常数:shielding constant化学位移:chemical shift国际纯粹与应用化学协会:IUPAC磁各向异性:magnetic anisotropy远程屏蔽效应:long range shielding effect结面:nodal plane自旋-自旋偶合:spin-spin coupling自旋-自旋分裂:spin=spin splitting单峰:singlet,s双峰:doublet,d三重峰:triplet,t四重峰:quartet五重峰:quintet六重峰:sextet偕偶:geminal coupling邻偶:vicinal coupling远程偶合:long range coupling磁等价:magnetic eqivalence自旋系统:spin system一级光谱:first order spectrum二级光谱(二级图谱):second order spectrumC-H光谱:C-H correlated spectroscopy,C-H COSY第十七章 质谱法质谱分析法:mass spectrometry质谱:mass spectrum,MS棒图:bar graph选择离子检测:selected ion monitoring ,SIM直接进样:direct probe inlet ,DPI接口:interface气相色谱-质谱联用:gas chromatography-mass spectrometry,GC-MS高效液相色谱-质谱联用:high performance liquid chromatography-mass spectrometry,HPLC-MS电子轰击离子源:electron impact source,EI离子峰:quasi-molecular ions化学离子源:chemical ionization source,CI场电离:field ionization,FI场解析:field desorptiion,FD快速原子轰击离子源:fast stom bombardment ,FAB质量分析器:mass analyzer磁质谱仪:magnetic-sector mass spectrometer四极杆质谱仪(四极质谱仪):quadrupole mass spectrometer原子质量单位:amu离子丰度:ion abundance相对丰度(相对强度):relative avundance基峰:base peak质量范围:mass range分辨率:resolution灵敏度:sensitivity信噪比:S/N分子离子:molecular ion碎片离子:fragment ion同位素离子:isotopic ion亚稳离子:metastable ion亚稳峰:metastable peak母离子:paren ion子离子:daughter含奇数个电子的离子:odd electron含偶数个电子的离子:even eletron,EE均裂:homolytic cleavage异裂(非均裂):heterolytic cleavage半均裂:hemi-homolysis cleavage重排:rearragement分子量:MWα-裂解:α-cleavage第十八章 色谱分析法概论色谱法(层析法):chromatography固定相:stationary phase流动相:mobile phase超临界流体色谱法:SFC高效毛细管电泳法:high performance capillary electroporesis,HPEC气相色谱法:gas chromatography,GC液相色谱法:liquid cromatography,LC超临界流体色谱法:supercritical fluid chromatography,SFC气-固色谱法:GSC气-液色谱法:GLC液-固色谱法:LSC液-液色谱法:LLC柱色谱法:column chromatography填充柱:packed column毛细管柱:capillary column微填充柱:icrobore packed column高效液相色谱法:high performance liquid chromatography,HPLC平板色谱法:planar平板色谱法:plane chromatography纸色谱法:paper chromatography薄层色谱法:thin layer chromatography,TLC薄膜色谱法;thiin film chomatography毛细管电泳法:capillary electrophoresis,CE分配色谱法:partition chromatography吸附色谱法:adsorpion chromaography离子交换色谱法:ion exchange chromatography,IEC空间排阻色谱法:steric exclusion chromatography,SEC亲和色谱法:affinity chromatography分配系数:distribution cofficient狭义分配系数:partition coefficient凝胶色谱法:gel chromatography凝胶渗透色谱法:gel permeation chromatography,GPC凝胶过滤色谱法:gel filtration chromatography,GFC渗透系数:permeation coefficien;Kp化学键合相色谱法:chemically bonded-phase chromatography分配系数:distribution coefficient靛菁绿:indocyanine气相色谱-傅立叶变换红外光谱:GC-FTIR第十九章 经典液相色谱法薄层色谱法:TLC吸附:adsorption活化:activation脱活性:deactivation交联度:degree of cross linking交换容量:exchange capacity薄层板:thin layer plate展开剂:developing solvent ,developer临界胶束浓度:criticak micolle concentration ,CMC相对比移值:relative Rf, Rr分离度:resolution ,R分离数:separation number,SN煅石膏:Gypsum羧甲基纤维素钠:CMC-Na吸收光谱联用:TLC-UV薄层色谱-荧光联用:TLC-F薄层色谱-红外吸收光谱联用:TLC-IR薄层色谱法:TLC-MS纸色谱法:paper chromatography上行展开:ascending development 下行法展开:descending development双向展开:two dimensional develoooment第二十章 气相色谱法气相色谱法:gas chromatography前延峰:leading peak拖尾峰:tailing peak对称因子:symmetry factor,fs保留时间:retention time保留体积:retention volume死时间:dead time调整保留时间:asjusted retention time半峰宽:peak width at half height,W1/2 or Y1/2峰宽:peak width,W等温线:isotherm理论塔板高度:height equivalent to atheoretical plate化学键合相:chemically bonded phase丁二酸二乙二醇聚酯:polydiethylene glycol succinate,PDEGS,DEGS高分子多孔微球:GDX苯乙烯:STY乙基乙烯苯:EST二乙烯苯:DVB涂壁毛细管柱:wall coated open tubular column,WCOT载体涂层毛细管柱:supprot coated open tubular column,SCOT热导检测器:thermal conductivity detector,TCD氢焰离子化检测器:hydrogen flame ionization detector,FID电子捕获检测器:electron capture detector ,ECD噪声:noise,N漂移:drift,d灵敏度:sensitivity检测限(敏感度):detectability,D,M分离度:resolution归一化法:normalization method外标法:external standardization第二十一章 高效液相色谱法高效液相色谱法:high performance liquid chromatography,HPLC高速液相色谱法:high speed LC,HSLC高压液相色谱法:high pressure LC,HPLC高分辨液相色谱法:high resolution LC,HRLC液固吸附色谱法(液固色谱法):liquid-solid adsorption chromatography,LSC液液色谱法:liquid-liquid chromatography,LLC正相:normal phase,NP反相:reversed phase,RP化学键合相色谱法:bonded phase chromatography,BPC十八烷基:octadecylselyl,ODS离子对色谱法:paired ion chromatography,PIC反相离子对色谱法:RPIC离子抑制色谱法:ion suppression chromatography,ISC离子色谱法:ion chromatography,IC手性色谱法:chiral chromatography,CC环糊精色谱法:cyclodextrin chromatography,CDC胶束色谱法:micellar chromatography,MC亲和色谱法:affinity chromatography,AC固定相:stationary phase化学键合相:chemically bonde phase封尾、封顶、遮盖:end capping手性固定相:chiral stationary phase,CSP恒组成溶剂洗脱:isocraic elution梯度洗脱:gradient elution紫外检测器:ultraviolet detector,UVD荧光检测器:fluorophotomeric detector,FD电化学检测器:ECD示差折光检测器:RID光电二极管检测器:photodiode array detector ,DAD三维光谱-波谱图:3D-spectrochromatogram蒸发光散射检测器:evaporative light scattering detector,ELSD安培检测器:ampere detector,AD高效毛细管电泳法:high performance capillary electrophoresis,HPCE淌度:mobility电泳:electrophoresis电渗:electroosmosis动力进样:hydrodynamic injection电动进样:electrokinetic injection毛细管区带电泳法:capillary zone electrophoresis,CZE胶束电动毛细管色谱:micellar electrokinetic capillary chromatography,MECC毛细管凝胶电泳:capillary gel electrophoresis,CGE

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