第十四章 红外分光光度法 红外线:infrared ray,IR 中红外吸收光谱:mid-infrared absorption spectrum,Mid-IR 远红外光谱:Far-IR 微波谱:microwave spectrum,MV 红外吸收光谱法:infrared spectroscopy 红外分光光度法:infrared spectrophotometry 振动形式:mode of vibration 伸缩振动:stretching vibration 对称伸缩振动:symmetrical stretching vibration 不对称伸缩振动:asymmetrical stretching vibration 弯曲振动:bending vibration 变形振动:formation vibration 面内弯曲振动:in-plane bending vibration,β 剪式振动:scissoring vibration,δ 面内摇摆振动:rocking vibration,ρ 面外弯曲振动:out-of-plane bending vibration,γ 面外摇摆振动:wagging vibration,ω 蜷曲振动:twisting vibration ,τ 对称变形振动:symmetrical deformation vibration ,δs 不对称变形振动:asymmetrical deformation vibration, δas 特征吸收峰:charateristic avsorption band 特征频率:characteristic frequency 相关吸收峰:correlation absorption band 杂化影响:hybridization affect 环大小效应:ring size effect 吸收峰的强度:intensity of absorption band 环折叠振动:ring prckering vibration 第十五章 原子吸收分光光度法 原子光谱法:atomic spectroscopy 原子吸收分光光度法:atomic absorption spectrophotometry,AAS 原子发射分光光度法:atomic emmsion spectrophotometry,AES 原子荧光分光光度法:atomic fluorescence spectrophotometry,AFS 第十六章 核磁共振波谱法 核磁共振:nuclear magnetic resonance,NMR 核磁共振波谱:NMR spectrum 核磁共振波谱法:NMR spectroscopy 扫场:swept field 扫频:seept frequency 连续波核磁共振:continuous wave NMR,CW NMR Fourier变换NMR:PFT-NMR,FT-NMR 二维核磁共振谱:2D-NMR 质子核磁共振谱:proton magnetic resonance spectrum,PMR 氢谱:1H-NMR 碳-13核磁共振谱:13C-NMR spectrum,13CNMR 自旋角动量:spin angular momentum 磁旋比:magnetogyric ratio 磁量子数:magnetic quantum number,m 进动:precession 弛豫历程:relaxation mechanism 局部抗磁屏蔽:local diamagnetic shielding 屏蔽常数:shielding constant 化学位移:chemical shift 国际纯粹与应用化学协会:IUPAC 磁各向异性:magnetic anisotropy 远程屏蔽效应:long range shielding effect 结面:nodal plane 自旋-自旋偶合:spin-spin coupling 自旋-自旋分裂:spin=spin splitting 单峰:singlet,s 双峰:doublet,d 三重峰:triplet,t 四重峰:quartet 五重峰:quintet 六重峰:sextet 偕偶:geminal coupling 邻偶:vicinal coupling 远程偶合:long range coupling 磁等价:magnetic eqivalence 自旋系统:spin system 一级光谱:first order spectrum 二级光谱(二级图谱):second order spectrum C-H光谱:C-H correlated spectroscopy,C-H COSY 第十七章 质谱法 质谱分析法:mass spectrometry 质谱:mass spectrum,MS 棒图:bar graph 选择离子检测:selected ion monitoring ,SIM 直接进样:direct probe inlet ,DPI 接口:interface 气相色谱-质谱联用:gas chromatography-mass spectrometry,GC-MS 高效液相色谱-质谱联用:high performance liquid chromatography-mass spectrometry,HPLC-MS 电子轰击离子源:electron impact source,EI 离子峰:quasi-molecular ions 化学离子源:chemical ionization source,CI 场电离:field ionization,FI 场解析:field desorptiion,FD 快速原子轰击离子源:fast stom bombardment ,FAB 质量分析器:mass analyzer 磁质谱仪:magnetic-sector mass spectrometer 四极杆质谱仪(四极质谱仪):quadrupole mass spectrometer 原子质量单位:amu 离子丰度:ion abundance 相对丰度(相对强度):relative avundance 基峰:base peak 质量范围:mass range 分辨率:resolution 灵敏度:sensitivity 信噪比:S/N 分子离子:molecular ion 碎片离子:fragment ion 同位素离子:isotopic ion 亚稳离子:metastable ion 亚稳峰:metastable peak 母离子:paren ion 子离子:daughter 含奇数个电子的离子:odd electron 含偶数个电子的离子:even eletron,EE 均裂:homolytic cleavage 异裂(非均裂):heterolytic cleavage 半均裂:hemi-homolysis cleavage 重排:rearragement 分子量:MW α-裂解:α-cleavage 第十八章 色谱分析法概论 色谱法(层析法):chromatography 固定相:stationary phase 流动相:mobile phase 超临界流体色谱法:SFC 高效毛细管电泳法:high performance capillary electroporesis,HPEC 气相色谱法:gas chromatography,GC 液相色谱法:liquid cromatography,LC 超临界流体色谱法:supercritical fluid chromatography,SFC 气-固色谱法:GSC 气-液色谱法:GLC 液-固色谱法:LSC 液-液色谱法:LLC 柱色谱法:column chromatography 填充柱:packed column 毛细管柱:capillary column 微填充柱:icrobore packed column 高效液相色谱法:high performance liquid chromatography,HPLC 平板色谱法:planar 平板色谱法:plane chromatography 纸色谱法:paper chromatography 薄层色谱法:thin layer chromatography,TLC 薄膜色谱法;thiin film chomatography 毛细管电泳法:capillary electrophoresis,CE 分配色谱法:partition chromatography 吸附色谱法:adsorpion chromaography 离子交换色谱法:ion exchange chromatography,IEC 空间排阻色谱法:steric exclusion chromatography,SEC 亲和色谱法:affinity chromatography 分配系数:distribution cofficient 狭义分配系数:partition coefficient 凝胶色谱法:gel chromatography 凝胶渗透色谱法:gel permeation chromatography,GPC 凝胶过滤色谱法:gel filtration chromatography,GFC 渗透系数:permeation coefficien;Kp 化学键合相色谱法:chemically bonded-phase chromatography 分配系数:distribution coefficient 靛菁绿:indocyanine 气相色谱-傅立叶变换红外光谱:GC-FTIR 第十九章 经典液相色谱法 薄层色谱法:TLC 吸附:adsorption 活化:activation 脱活性:deactivation 交联度:degree of cross linking 交换容量:exchange capacity 薄层板:thin layer plate 展开剂:developing solvent ,developer 临界胶束浓度:criticak micolle concentration ,CMC 相对比移值:relative Rf, Rr 分离度:resolution ,R 分离数:separation number,SN 煅石膏:Gypsum 羧甲基纤维素钠:CMC-Na 吸收光谱联用:TLC-UV 薄层色谱-荧光联用:TLC-F 薄层色谱-红外吸收光谱联用:TLC-IR 薄层色谱法:TLC-MS 纸色谱法:paper chromatography 上行展开:ascending development 下行法展开:descending development 双向展开:two dimensional develoooment 第二十章 气相色谱法 气相色谱法:gas chromatography 前延峰:leading peak 拖尾峰:tailing peak 对称因子:symmetry factor,fs 保留时间:retention time 保留体积:retention volume 死时间:dead time 调整保留时间:asjusted retention time 半峰宽:peak width at half height,W1/2 or Y1/2 峰宽:peak width,W 等温线:isotherm 理论塔板高度:height equivalent to atheoretical plate 化学键合相:chemically bonded phase 丁二酸二乙二醇聚酯:polydiethylene glycol succinate,PDEGS,DEGS 高分子多孔微球:GDX 苯乙烯:STY 乙基乙烯苯:EST 二乙烯苯:DVB 涂壁毛细管柱:wall coated open tubular column,WCOT 载体涂层毛细管柱:supprot coated open tubular column,SCOT 热导检测器:thermal conductivity detector,TCD 氢焰离子化检测器:hydrogen flame ionization detector,FID 电子捕获检测器:electron capture detector ,ECD 噪声:noise,N 漂移:drift,d 灵敏度:sensitivity 检测限(敏感度):detectability,D,M 分离度:resolution 归一化法:normalization method 外标法:external standardization 第二十一章 高效液相色谱法 高效液相色谱法:high performance liquid chromatography,HPLC 高速液相色谱法:high speed LC,HSLC 高压液相色谱法:high pressure LC,HPLC 高分辨液相色谱法:high resolution LC,HRLC 液固吸附色谱法(液固色谱法):liquid-solid adsorption chromatography,LSC 液液色谱法:liquid-liquid chromatography,LLC 正相:normal phase,NP 反相:reversed phase,RP 化学键合相色谱法:bonded phase chromatography,BPC 十八烷基:octadecylselyl,ODS 离子对色谱法:paired ion chromatography,PIC 反相离子对色谱法:RPIC 离子抑制色谱法:ion suppression chromatography,ISC 离子色谱法:ion chromatography,IC 手性色谱法:chiral chromatography,CC 环糊精色谱法:cyclodextrin chromatography,CDC 胶束色谱法:micellar chromatography,MC 亲和色谱法:affinity chromatography,AC 固定相:stationary phase 化学键合相:chemically bonde phase 封尾、封顶、遮盖:end capping 手性固定相:chiral stationary phase,CSP 恒组成溶剂洗脱:isocraic elution 梯度洗脱:gradient elution 紫外检测器:ultraviolet detector,UVD 荧光检测器:fluorophotomeric detector,FD 电化学检测器:ECD 示差折光检测器:RID 光电二极管检测器:photodiode array detector ,DAD 三维光谱-波谱图:3D-spectrochromatogram 蒸发光散射检测器:evaporative light scattering detector,ELSD 安培检测器:ampere detector,AD 高效毛细管电泳法:high performance capillary electrophoresis,HPCE 淌度:mobility 电泳:electrophoresis 电渗:electroosmosis 动力进样:hydrodynamic injection 电动进样:electrokinetic injection 毛细管区带电泳法:capillary zone electrophoresis,CZE 胶束电动毛细管色谱:micellar electrokinetic capillary chromatography,MECC 毛细管凝胶电泳:capillary gel electrophoresis,CGE 筛分:sieving |