氢氟酸 Hydrofluoric Acid - HF 特性 Characteristics 健康危害 Health hazards 急救步骤 First aid procedures 个人防护用品 Personal protective equipment 处理与储运 Handling and transportation 医务治理 Medical treatment 医务治理预先安排的必要 Importance of pre-arrangement for medical treatment 急性接触氢氟酸死亡 Fatality on acute HF exposure 衣服没除去 Clothing not removed 沉浸于游泳池 immersed in swimming pool 40分后救护车 40min ambulance arrived 特别护理 intensive care 7天后右腿截去 7 days right leg amputated 15天各种器官失效-死 15 days multi-organ failure - die 针孔接触 PIN-HOLE CONTACT 清洗空罐 washing empty container 针孔手套 pin-hole gloves 第二天烧伤手指 second day burning finger 拔除指甲 remove finger nail 注射药剂 medical injection 性质 Properties 无色/冒烟液体 Colorless/fuming liquid 涩味 acrid odor 酸碱度1.0 (0.1 摩尔 溶解) pH 1.0 (0.1M solution) 不相容的:氨,碱 ,硫酸,有机物,橡胶,皮革,玻璃等incompatible: NH3, NaOH, H2SO4, alkalis, organic, rubber, leather, water, glass….. 避免:湿气 Avoid: moisture 健康危害 Health hazard 危害不立刻显出Harmful not immediately apparent 吸入:严重腐蚀呼吸系统 Inhalation: severely corrosive to respiratory system 皮肤接触:腐蚀性,严重的皮肤烧伤不立刻显出、疼痛, 延迟8小时或更长:很快渗透皮肤-内肤与骨骼 skin contact: corrosive, serious skin burns not immediately apparent/painful, delay 8 hours or longer: F ion readily penetrate skin - deep tissue and bone 健康危害 Health hazard 眼睛接触:腐蚀 Eye contact: corrosive 慢性暴露:>6 毫升/天- 氟蚀病,骨骼/关节伤害 chronic exposure: >6gm/day - fluorosis, bone/joint damage… 吞入:腐蚀消化系统,肾功能失效 ingestion: corrosive digestive tract, kidney dysfunction 恶化现有情况 aggravation existing conditions 急救 First aid 工作前要有详细计划 Detailed planned before work 吸入:立刻寻求医务治疗 inhalation: immediate medical help 吞入: 立刻寻求医务治疗 ingestion: immediate medical help 皮肤:长时间清洗,除去衣服….. 立刻寻求医务治疗 skin: wash long time, remove clothing, …..medical help 眼睛: 长时间清洗 ….. 立刻寻求医务治疗 eye: wash long time …..medical help 预安排医务治疗 Pre-arrange medical help 通知/预先安排可能的事件 Inform/prearrange possible incident 备好药物/设备 ready medicines/facilities 知识/物料安全资料表 information/MSDS 信件通知医生 note to physician 处理和贮藏 Handling and storage 紧密闭PE容器 Tightly closed PE container 凉爽/乾燥地方足够通风 cool/dry place adequate ventilation 避免损害 protect damage 围堵/泄漏 containment/spill 特殊材料 /供应商科技 special materials/technology from supplier 遵守/跟随警告 observe/follow warning 使用安全防护用品 Use PPE 定点/全面通风设备 Local preferred/general ventilation 消除热、火源 remove ignition source 泄漏 - 疏散地区 spill - evacuate area 处理- 干碳酸镁,碳酸钠,石灰 treat - dry MgSO4, soda ash/slaked lime 收集 - 废物处理 collect - disposal 清理/中和 clean/neutralize 个人的保护 Personal protection 防毒面具,正确类型 Respiratory, correct type 皮肤:防护衣服,长靴,安全鞋, PVC手套, 化学眼罩 /面罩,围裙 skin: protective clothing, boots/safety shoes, PVC gloves, chemical goggles/full face shield, coveralls…. 眼睛:眼罩/面罩 Eye: goggles/full face shield 氢氟酸安全 HF SAFETY 毒药,危险物,腐蚀剂 Poison, danger, corrosive 极端危险的液体/气体 extremely hazardous liquid/vapor 严重烧伤不立刻痛苦/显出 sever burn not immediate painful/visible 致命如吞下或吸进 fatal if swallowed or inhaled 烧伤皮肤,眼睛,呼吸系统 burn skin, eyes, respiratory tract 造成骨骼伤害 cause bone damage 避免进入眼睛,皮肤,衣服 Do not get in eyes, on skin, on clothing 不要吸入气体 do not breath vapor 凉后才打开 cool before opening 足够通风 adequate ventilation 彻底洗清手 wash hand thoroughly 贮藏在紧密关上容器 store in tightly close container 立刻寻求医务治理 CALL MEDICAL HELP IMMEDIATELY 绝对遵守指示、警告 Strictly follow instruction/precaution 绝对使用个人防护用品 Always use PPE
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